Some additional thoughts and numbers on #QuantumScape. Long story short: my estimate is that an "anode-free" solid state cell should fetch ~350 Wh/kg, in the absence of some new miracle positive electrode. Bit lower than 380-480 Wh/kg QS have stated. Thread... 1/
My starting point for my (medium crude) calculations is Tesla - they have probably the most energy-dense +ve on the market now: NCA w/ 90% Ni and a high capacity of ~4.5 mAh/cm2. My cell model gets pretty close to the Model 3 2170 cell numbers, so it's an ok starting point. 2/ Image
My gut feeling is that QS are going to be using a similar Ni-rich electrode, despite mentions of new conversion cathodes - because I think the latter is one technology leap too many for me to believe without any good evidence to the contrary... 3/
In some of their patents, QS make mention of 4 mAh/cm2 tests of their Li electrodes, so I'm going to assume this is their target and is achievable. I'm also assuming these will be pouch cells. So I'm going to model a pouch cell with NCA, 4 mAh/cm2, and guesstimate dimensions 4/
This is what I got, 23 x 16 cm cell with 20 electrode layers. Bit higher gravimetric and bit lower volumetric compared to cylindrical, sounds ok. Not sure I have a good point of comparison to a real cell but capacity-wise this is around the level of many other EV cells now 5/ Image
For the solid state cell, I have to make some guesses. I'm assuming the electrolyte layer is 15-25 µm (open Q as to whether this is achievable; current batteries have 10-15 µm plastic separators), and that the electrolyte is dense "LLZO" as again patents might suggest. 6/
And here's my estimate: 355 ± 41 Wh/kg, slightly overlapping with QS's 380-480 Wh/kg. But >1000 Wh/L volumetric (taking into account volume expansion of the cell after the Li is plated). +31% ± 15% gravimetric and +60 ± 14% compared to the Li-ion version 7/ Image
Out of interest, here's the same cell but if it would have a pure silicon anode as well, which has been a topic of conversation in the last week - I make it a bit lower gravimetric energy, but around the same volumetric. 8/ Image
A big question is how thin can the solid electrolyte membrane really be made? Shaving 10 µm off to reach the level of today's polyethylene separators will add 30 Wh/kg on its own by my numbers. Another is volume expansion, this whole cell would expand ~22% during charge 9/
*If* such cells could be realised, then there's further possible advantages. A solid state cell won't have the same propensity towards thermal runaway (though I don't believe in "intrinsically safe") - so cooling requirements in packs etc could be reduced, saving more weight 10/
Of course, plenty of questions still abound. The only publicly available information points to only relatively small, single layer pouch cells so far. Deployment in a production car in 2025 seems far fetched to me, though they do have strong backing. 11/
I'll be watching with interest. My default position is to be skeptical, but I still think the challenges of SS and Li metal are solvable, and if there is going to be any battery tech offering a big step up from Li-ion, it's probably this or something like it. /end, maybe
P.S.; 480 Wh/kg could be achievable with some very thick electrodes and some very thin (~10 µm) electrolytes, and some optimism about minimising the amount of LLZO in the electrode. Plausible, maybe, but surely very very hard to achieve Image

• • •

Missing some Tweet in this thread? You can try to force a refresh
 

Keep Current with Matt Lacey

Matt Lacey Profile picture

Stay in touch and get notified when new unrolls are available from this author!

Read all threads

This Thread may be Removed Anytime!

PDF

Twitter may remove this content at anytime! Save it as PDF for later use!

Try unrolling a thread yourself!

how to unroll video
  1. Follow @ThreadReaderApp to mention us!

  2. From a Twitter thread mention us with a keyword "unroll"
@threadreaderapp unroll

Practice here first or read more on our help page!

More from @mjlacey

28 Jan
Another creative excuse from a Swedish public official

Head of @Folkhalsomynd says: "I missed that the time was in the commuter hours", after being spotted breaking rule on face masks on public transport during commuter hours, on his regular commute

svt.se/nyheter/lokalt… /1
I'm still impressed by our state epidemiologist's brazen "I'm standing far in front of the others", after being photographed manifestly not keeping distance at a Gothenburg restaurant last year

friatider.se/anders-tegnell… /2
And more recently, Prime Minister Stefan Löfvén being spotted in a shopping mall before Christmas, 2 days after imploring the public not to visit them: "I have never shopped online"

svt.se/nyheter/inrike… /3
Read 4 tweets
8 Dec 20
Seems my threading earlier on @QuantumScapeCo went a bit bananas, so I'll collect some general post-presentation post-dinner thoughts/questions/observations under here... 1/
So finally we got to see some cycling data: 1 hour charge/discharge, practical capacities, >800 cycles achieved seemingly quite readily - for a so-called anode free Li metal cell these results are very impressive! 2/
Key caveat though - these are single layer pouch cells, which need to be brought up to many (20+) layers to commercialise. This is presumably not easy else I'd expect a company at this stage to show proof of concept multilayer cells... 3/
Read 14 tweets
8 Dec 20
Settling down for the much-anticipated #QuantumScape reveal. A little taste of this already on their website, link below. Feels like a thread coming on... ir.quantumscape.com/news/news-deta…
Interesting to hear from the start a clear disclaimer about this showcase presenting "forward looking statements", making clear that reality might differ from expectation outside of QS's control
Recap of investment: they're well-funded by now, having raised ~$1.5bn so far, about ~$300m has gone into R&D so far. VW are committed to the tune of $300m, and have a joint venture with QS for manufacturing. Now they're listed, market cap was ~$15bn last I checked...
Read 20 tweets

Did Thread Reader help you today?

Support us! We are indie developers!


This site is made by just two indie developers on a laptop doing marketing, support and development! Read more about the story.

Become a Premium Member ($3/month or $30/year) and get exclusive features!

Become Premium

Too expensive? Make a small donation by buying us coffee ($5) or help with server cost ($10)

Donate via Paypal Become our Patreon

Thank you for your support!

Follow Us on Twitter!