Why do models underestimate the rate of ocean deoxygenation?

Well... @altagliabue and I used a suite of models and observations to try and answer this question.

agupubs.onlinelibrary.wiley.com/doi/10.1029/20…

@livunioceansci @Env_Sci Image
Turns out that changes in ventilation in models are weaker than in the real ocean.

(We used CFCs and SF6 measurements to estimate ideal age) Image
But along the Eastern Boundary Upwelling Zones, which host low-O2 zones, biogeochemical O2 demand is important. Image
This suggests that differences in biogeochemical model architecture may underly the divergent trends in low-O2 zones.

That's a problem if we want to be more confident in model projections for these important regions in the coming decades.
For example, take the the Canary and Benguela upwelling systems off West Africa.

In the Canary, a decrease in primary production and a shift to smaller phytoplankton lead to oxygenation. In the Benguela, the opposite occurred. Image
Overall:
1. Large-scale deoxygenation is principally physical
2. Except in the eastern boundary upwelling systems
3. Models underestimate real trends largely due to physical inconsistencies (coarse resolution)

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More from @PearseJBuchanan

28 Oct
Models project that #ocean #phytoplankton will become increasingly starved of #nitrogen as #climatechange progresses.

If realised, this has implications for #fisheries.

But how can we monitor this change in the real ocean?

Nitrogen isotopes!
rdcu.be/cAlW2 Image
What are nitrogen (N) isotopes?

There is a heavy isotope (15-N) and a light isotope (14-N).

Some processes prefer to use 14-N more than 15-N. When phytoplankton use nitrogen, they prefer 14-N.

This increases the ratio of 15-N to 14-N in seawater. Image
But when N is scarce, phytoplankton have less preference.

Like if there was only one kind of pizza at a party, you don't have the option of being picky (you have to have the pineapple).

In this case, phytoplankton no longer increase the ratio of 15-N to 14-N in seawater. Image
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