1/7 A bit of chemistry of the Atlas V rocket. Initial liftoff is achieved with “booster” solid composite propellant that contains ammonium perchlorate, aluminum powder, and hydroxy terminated polybutadiene (HTPB) as the binder system.

#Chemtwitter #Space #STEM
2/7 Aluminum only makes up a small amount of the overall formulation of the booster, but is very important. It catalyzes efficient and clean combustion, and maximizes the burning rate of the solid booster propellant mixture.

#Chemtwitter #Space #STEM
3/7 After the boosters finish their initial work, they separate from the rocket, and the first stage engine takes over. In the case of the Atlas V, it’s a common core booster propellant known as Kerolox.

#Chemtwitter #Space #STEM
4/7 Kerolox contains liquid oxygen (LOX) for the oxidizer, and RP-1 for the fuel. RP-1 is a highly refined kerosene. It contains negligible water, sulfur, alkenes or aromatics. This is critical to prevent polymerization, and gumming up of the engine.

#Chemtwitter #Space #STEM
5/7 After the first stage finishes burning, the second stage engine takes over. Known as Centaur, this contains LOX and liquid hydrogen (LH2) for the fuel. The specific impulse of this system is very high, operating smoothly in very cold environments.

#Chemtwitter #Space #STEM
6/7 So when you see a fuel dump of the Atlas V, this is excess LH2/LOX. This is common practice to minimize an explosion risk, and poses zero threat to the environment. LH2 reacts with oxygen to give water and heat.

#Chemtwitter #Space #STEM
7/7 It was cloudy in Maryland, so I couldn’t see the fuel dump’s brilliant blue light this time. But I’ve seen them in the past, and I’d recommend it for anybody that has an interest in space.

#Chemtwitter #Space #STEM

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More from @JJSabatini

Jan 15
1/6 If you get invited for an interview, then it means that the organization asking to interview you is genuinely interested in you, your skill set, and what you potentially have to offer. So know this going in.

@PhDVoice #phdchat #AcademicChatter #AcademicTwitter
2/6 To do well in an interview, you will need to talk about your accomplishments. Talk about your research, what you did that advanced the knowledge of the field, and how you can work well in a team environment.

@PhDVoice #phdchat #AcademicChatter #AcademicTwitter
3/6 If you have published, or presented your work, talk about it, and discuss why the research you did was impactful. Do not be afraid to talk about yourself. It’s not boasting. It’s selling yourself and trying to get the job

@PhDVoice #phdchat #AcademicChatter #AcademicTwitter
Read 6 tweets
Sep 9, 2020
(1/25) I am writing this thread concerning grad student life in organic synthesis. Some folks will agree with it (though perhaps not openly). Others may be very upset. Either way is OK. But here are some stories, thoughts, and advice

#chemtwitter #realtimechem @RealTimeChem
(2/25) I began grad school in June 2004, working in the lab of (now retired) Prof. James A. Marshall. He was one of Prof. Ireland’s first graduate students (1957-1960). I joined the Marshall group not because it was easy, but because it was hard. The hard is what made it great
(3/25) Expectations were laid out the first day I arrived. Dr. Marshall was hands off, expected you to generate your own ideas, and understood that lots of reactions don’t work. The PhD is earned by solving problems, and problems won’t fix themselves. You need to put the time in
Read 25 tweets
Aug 22, 2020
(1/5) My two cents from someone in the energetic materials arena. Med chem is equivalent to small molecule discovery of new explosive and propellant ingredients. Process chem is the scale-up of these materials for testing purposes.
#chemtwitter #RealTimeChem @RealTimeChem
(2/5) In the discovery phase, cost of reagents, cost of synthesis, and length of the synthesis route aren’t an immediate priority. Goal is to make the new stuff, and get preliminary data to see if it’s even worth scaling-up.
#chemtwitter #RealTimeChem @RealTimeChem
(3/5) If the new energetic fails thermal analysis, is found to be too sensitive to work with, or is incompatible with ingredients it will come into contact with in a formulation, then its dead. This can be determined with little material

#chemtwitter #RealTimeChem @RealTimeChem
Read 19 tweets
Aug 10, 2020
(1/25) Having received some DMs on the subject, I would like to tell you all about military technologies, and how they impact our daily lives. This will be a long thread that I hope you’ll read and think about.

#chemtwitter #realtimechem @RealTimeChem
(2/25) The internet (which originated from the ARPANET), computers, GPS technologies, duct tape, drones, weather radar, microwave ovens,  digital cameras, jet engines, synthetic rubber, superglue, canned food, jeep vehicles,

#chemtwitter #RealTimeChem @RealTimeChem
(3/25) The mass production of penicillin, wristwatches, walkie-talkies, night vision, sanitary napkins, freeze drying, the EpiPen, Jerrycans, blood banks and blood transfusions, ambulances, aviator sunglasses, and the entire Space Program

#chemtwitter #reatimechem @RealTimeChem
Read 25 tweets

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