It's like this entire administration is made up of James Bond villains. 
All right, let's break this down.
Secretary of State Rex Tillerson is Karl Stromberg. 
Secretary of the Treasury Steve Mnuchin is Dr. No 
Secretary of Defense Jim Mattis is Brad Whitaker 
Attorney General Jeff Sessions is Dominic Greene 
Secretary of the Interior Ryan Zinke is Jaws 
Secretary of Agriculture Sonny Perdue is Ernst Stavro Blofeld 
Secretary of Commerce Wilbur Ross is Renard 
Secretary of Labor Alex Acosta is Francisco Scaramanga 
HUD Secretary Dr. Ben Carson is Dr. Kananga 
Secretary of Transportation Elaine Chao is Irma Bunt 
Secretary of Energy Rick Perry is Ernst Stavro Blofeld (new version) 
Secretary of Education Betsy DeVos is Raoul Silva 
White House Chief of Staff John Kelly is Red Grant 
Former White House Chief Strategist Steve Bannon is Auric Goldfinger 
Former White House Deputy Assistant Seb Gorka is Hugo Drax 
White House Senior Advisor Stephen Miller is Le Chiffre 
Ivanka Trump and Jared Kushner are Miranda Frost and Gustav Graves (via @_datanotshown_ ) 
Vice President Mike Pence is Emil Largo 
President Donald J. Trump is Max Zorin 
All right, a few more in the wider Trumposphere.
Trump's personal lawyers Jay Sekulow and Ty Cobb are Mr. Wint and Mr. Kidd. 
Trump laywer Michael Cohen is Prof. Joe Butcher 
Carter Page is Zao 
Former National Security Adviser General Michael Flynn as General Arkady Grigorovich Ourumov 
Former Trump campaign head Paul Manafort as Kamal Khan 
First Lady Melania Trump is Electra King 
Counselor to the President Kellyanne Conway is Rosa Klebb
(hat tip to whoever suggested this earlier in the thread)
(hat tip to whoever suggested this earlier in the thread)
White House Communications Director Anthony Scaramucci is Nick Nack 
White House Press Secretary Sean Spicer is General Orlov 
National Security Adviser H.R. McMaster is KGB Chief A.A. Gogol 
Roger Stone is Odd Job 
We've come this far. Let's end this thing.
Julian Assange is Maximillian Largo 
Former HHS Secretary Tom Price is Elliott Carver (played by Jonathan Pryce!) 
Donald Trump Jr. and Eric Trump are Mischka and Grischka 
Roger Ailes is Dr. Carl Mortner 
EPA Director Scott Pruitt is Necros 
And Roy Moore is Sheriff J.W. Pepper 
Some final loose ends, and I'm done. I promise. Maybe.
(Fixing typos)
Sheriff David Clarke as Baron Samedi 
Sheriff Joe Arpaio is Milton Krest 
George Papadopolous is Carlos 
Dr. Harold Bornstein is Henry Gupta 
Nigel Farage is Ernst Stavro Blofeld (Diamonds Are Forever version) 
Rob Goldstone is Valentin Zukov
(thanks to a comment in the replies)
(thanks to a comment in the replies)
Corey Lewandowski is Elvis 
Katrina Pierson is Fatima Blush 
Tucker Carlson is Will Truman-Lodge 
Sean Hannity is General Koskov 
Milo Yiannopoulos is Boris Grishenko 
FCC Chairman Ajit Pai is Tee-Hee Johnson 
Budget Director Mick Mulvaney is Mister Bullion 
Steve Doocy and Brian Kilmeade are Bambi and Thumper 
Geraldo Rivera is Angelo Palazzi 
CIA Director Mike Pompeo is Alec Trevelyan 
Tom Cotton is Gobinda 
Trump's lawyer John Dowd is Sandor 
James O'Keefe (in '70s pimp disguise) is Kananga (in Mr. Big disguise) 
Paul Ryan is Mr. Stamper 
Mitch McConnell is Bert Saxby 
Vladimir Putin is Tov Kronsteen 
Devin Nunes is Alex Dimitrios 
Lindsey Graham is Pussy Galore 
Chuck Grassley is Emil Locque 
Press Secretary Sarah Huckabee Sanders is Mr. Kil 
Secretary of Homeland Security Kirstjen Nielsen is Valenka 
Nominee for Secretary of Health and Human Services Alex Azar is Sasha Davidov 
Bill O'Reilly is Mr. White 
Jason Chaffetz is Ed Killifer 
Libertarian Party nominee Gary Johnson is Professor R.J. Dent 
UN Ambassador Nikki Haley is Naomi 
Jeffrey Lord is Vladimir Popov 
Laura Ingraham is Jenny Flex 
Governor Chris Christie is Whisper 
Alex Jones is Colonel Heller 
Rudy Guiliani (disguised as a blonde) is Jacques Bouvar (disguised as a blonde) 
Chief Economic Adviser Gary Cohn is Ernst Stavro Blofeld (On Her Majesty's Secret Service version) 
Former Chief of Staff Reince Priebus is Max Denbigh 
Trump Campaign Communications Director Jason Miller is Mr. Hinx 
Deputy Campaign Manager David Bossie is General Madrano 
Stormy Daniels is Fiona Volpe 
